Fully automated analysis of speciated halogens in pyrolysis oil
Aug 02 2022
Pyrolysis oil, sometimes also known as bio-crude or bio-oil, is a synthetic fuel that can be used as an alternative substitute for petroleum. It is obtained by heating biomass (wood/ algae or even plastics/polymers) in an oxygen-free reactor, at a temperature of about 500 °C with subsequent cooling. Pyrolysis is a well-known and proven technique for the decomposition of organic or non-organic material at elevated temperatures in the absence of oxygen into oil and other constituents. In second-generation biofuel applications—forest and agricultural residues, waste wood, yard waste, and energy crops can also be used as feedstock.
The end product of pyrolysis oil resembles the characteristics of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. The high oxygen content results in non-volatility, corrosiveness, immiscibility with fossil fuels, thermal instability, and a tendency to polymerise when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading and forms a more stable end-product that can be used in pure form or in blends as a fuel alternative.
One of the standard specifications for analysis of pyrolysis biofuel is covered in the ASTM norm D7544-12. This norm only covers the analysis of total sulphur (for combustion analysis), the speciated analysis for halogens (in particular: chloride, fluoride, and bromide) are not mentioned.
A key difference is that nowadays many other waste basis materials like municipal waste, recycling of plastics/polymers, or semi-synthetics are being used to produce pyrolysis oil products. These feed bases may contain fluoride, chloride, and/or bromide and high levels are to be prevented.
TE Instruments developed a fully automated setup for the analysis of halogens in pyrolysis oils and their feed base. The Xprep C-IC is a compact sample preparation system covering oxidative pyro-hydrolytic combustion, fraction collection, and sample injection towards any ion chromatograph available on the market. The Xprep C-IC can introduce samples via optimised direct injection (liquids module) and/ or via a conventional boat-inlet (boat module) into a horizontal furnace. This automated sample-prep solution reduces the complexity of sample transfer and significantly improves user convenience. Solid sample material can also be introduced into the combustion furnace, via the Newton autosampler with a standard sample capacity of 20 sample positions (extendable up to 60).
In This Edition Articles - Climate-Friendly Flaring Vent Gas Analysis To Ensure Complete Combustion - Some Recent Advancements in Wind Energy Technologies - For the latest developments in a...
View all digital editions
Oct 08 2023 Accra,Ghana
Oct 09 2023 Benghazi, Libya
Oct 09 2023 Cape Town, South Africa
Oct 10 2023 Galveston, TX, USA
Oct 10 2023 Lyon, France